Mineral and geochemical features of the porphyry copper ores at Koktaszhal deposit, central Kazakhstan

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Authors:


A. N. Kopobayeva, orcid.org/0000-0002-0601-9365, Abylkas Saginov Karaganda Technical University, Karaganda, Republic of Kazakhstan

K. E. Toleubek*, orcid.org/0000-0003-2126-8084, Abylkas Saginov Karaganda Technical University, Karaganda, Republic of Kazakhstan, e-mail: This email address is being protected from spambots. You need JavaScript enabled to view it.

А. Amangeldikyzy*, orcid.org/0000-0002-6665-8804, Abylkas Saginov Karaganda Technical University, Karaganda, Republic of Kazakhstan, e-mail: This email address is being protected from spambots. You need JavaScript enabled to view it.

N. S. Askarova, orcid.org/0000-0002-2103-6198, Abylkas Saginov Karaganda Technical University, Karaganda, Republic of Kazakhstan

* Corresponding authors e-mail: This email address is being protected from spambots. You need JavaScript enabled to view it.; This email address is being protected from spambots. You need JavaScript enabled to view it.


повний текст / full article



Naukovyi Visnyk Natsionalnoho Hirnychoho Universytetu. 2025, (5): 023 - 031

https://doi.org/10.33271/nvngu/2025-5/023



Abstract:



Purpose.
To study mineralogical and geochemical characteristics of Koktaszhal porphyry copper deposit in order to reveal regularities of porphyry copper ore formation and develop exploration criteria.


Methodology.
The research applies modern mineralogical and geochemical approaches including XRF (X-ray fluorescence), optical emission spectrometry (ICP-OES), X-ray diffraction analysis (XRD), chemical analysis and phase analysis, as well as analysis of literature and library materials.


Findings.
Complex mineralogical and geochemical studies of ores of Koktaszhal deposit revealed a complex structure conditioned by porphyry copper mineralization and zonal distribution of its components. Geochemical analysis revealed the prevalence of SiO2, Al2O3 and Na2O in the ore composition. Comparison of oxide and sulphide ore analyses determined a clear spatial and geochemical differentiation of ore components, which reflects different stages of ore formation. It was found that in oxide ore 79.5 % of copper is associated with malachite and azurite, and in sulphide ore, 79 % of copper is associated with bornite. The supergene alteration zone is enriched in Bi, Pb, Co, Ni, which indicates the migration of these elements in the weathering zones, while the sulphide zone is characterized by stable content of Mo, Sb and Ag, which confirms the primary-sulphide nature of the studied mineralization and its formation under low temperature conditions. X-ray diffraction and electron microscopic analyses revealed predominance of quartz, albite, muscovite and other silicates, which confirms the presence of intensive processes of argillisitization and sericitization. The results of thermogravimetric analysis showed high thermal stability of the ore and predominance of thermally stable minerals. The results obtained make it possible to clarify the morphology of ore bodies, to identify geochemical criteria for exploring and evaluating porphyry copper objects, as well as to substantiate directions for ore processing optimization.


Originality.
The porphyry copper mineralization of Koktaszhal deposit was comprehensively researched using modern analytical and statistical methods. For the first time, a complex interpretation of mineralogical and geochemical characteristics of ores was performed taking into account their spatial variability and influence of tectonic faults. The research identified new genetic features reflecting the stages of fluid mineralization, as well as diagnostic parameters allowing reliable differentiation of ore types.


Practical value.
The obtained results can be used in ore bodies modelling and planning of exploration works at the stage of assessment and revaluation of reserves of porphyry copper deposits of Central Kazakhstan.



Keywords:
porphyry copper ores, Koktaszhal, geochemistry, mineralogy, clarke, oxide ores, sulphide ores

References.


1. Bai, Y., Hu, W., & Wu, Y. (2021). Strategic significance of copper porphyry deposits in global economic development. Resources, 10(3), 34. https://doi.org/10.3390/resources10030034

2. Calderón, C., & López, R. A. (2020). The impact of copper exports on economic growth: Evidence from Chile. Resources Policy, 68, 101782. https://doi.org/10.1016/j.resourpol.2020.101782

3. Lee, J., Chen, K., & Liu, X. (2019). Emerging trends in copper demand: Implications for copper porphyry mining. Minerals, 9(10), 322. https://doi.org/10.3390/min9100322

4. Wang, H., Zhang, X., & Wu, Y. (2018). Global copper supply and demand forecast: The economic implications of copper mining. Mineral Economics, 31(2), 199-206. https://doi.org/10.1007/s13563-018-0156-9

5. Arnaud, L., & Gaillard, F. (2020). Sustainable development in copper mining: Challenges and opportunities. Journal of Cleaner Production, 261, 121161. https://doi.org/10.1016/j.jclepro.2020.121161

6. Kurmangaliyev, A., Baimukhanov, A., & Zharikov, A. (2017). The role of Kazakhstan in global copper production. Resources Policy, 52, 189-196. https://doi.org/10.1016/j.resourpol.2017.03.004

7. Baimukhanov, A., Zharikov, A., & Turgumbayev, A. (2020). Geological overview of major copper deposits in Kazakhstan. Geological Journal, 55(7), 3656-3668. https://doi.org/10.1002/gj.3750

8. Zharikov, A., Turgumbayev, A., & Kovalev, I. (2020). The development of the copper mining industry in Kazakhstan. Minerals, 10(5), 444. https://doi.org/10.3390/min10050444

9. Turgumbayev, A., Kovalev, I., & Zhukov, N. M. (2018). Analysis of copper exports from Kazakhstan: Economic implications. Economic Studies Journal, 47(2), 246-261.

10.      Kovalev, I., Zhukov, N. M., & Abdulin, A. A. (2021). Climate change and sustainable mining practices in Kazakhstan. Journal of Cleaner Production, 285, 124812. https://doi.org/10.1016/j.jclepro.2020.124812

11.      Zhukov, N. M., Abdulin, A. A., Bespaev, Kh. A., Votsalevsky, E. S., Daukeev, S. Zh., & Miroshnichenko, L. A. (1997). Copper deposits of Kazakhstan: Reference book. Almaty: [b.i.].

12.      Duzhnikova, Y. V., Kryazheva, T. V., & Toleubek, K. Ye. (2020). Koktaszhal ore field (Central Kazakhstan) research results. Naukovyi Visnyk Natsionalnoho Hirnychoho Universytetu, (3), 5-12. https://doi.org/10.33271/nvngu/2020-3/005

13.      Geologiya Kazakhstana (2001). Geology of Kazakhstan, (1), 41-58.

14.      Duzhnikova, Ye. V., Kryazheva, T. V., & Kenzhin, B. M. (2019). The mineral composition of the ores and the conditions of their formation at the Koktaszhal deposit. Bulletin of the East Kazakhstan State Technical University named after D. Serikbayev, 1(83), 3-8. Retrieved from https://www.ektu.kz/files/vestnik/geo1_2019.pdf

15.      Chitalin, A. V., Grigoriev, S. V., Korolkova, N. V., & Shcherbakov, D. V. (2024). Porphyry copper and epithermal gold-silver mineralization of the Baemskaya zone. IGEOTECH, (2), 5-25. Retrieved from https://igeotech.ru/wp-content/uploads/2024/06/chitalin-i-dr_baimskaya-zona_2024.pdf

16.      Vinogradov, A. P. (1962). Average content of chemical elements in igneous rocks of the Earth. Geokhimiya, (7), 555-571.

17.      Glukhan, I.V., & Serykh, V.I. (1996). The Mean Chemical Compositions (Regional Clarkes) of Igneous Rocks of Central Kazakhstan. In V. Shatov, & R. Seltman (Eds.) (1996). Granite-Related Ore Deposits of Central Kazakhstan and Adjacent Areas, (pp. 269-286). SPb.

18.      Serykh, V. I., & Kopobayeva, A. N. (2019). Patterns of distribution of rare metal deposits in Central Kazakhstan. News of the National Academy of Sciences of the Republic of Kazakhstan, Series of Geology and Technical Sciences, 143-150. https://doi.org/10.32014/2019.2518-170X.18

19.      Portnov, V. S., Kopobayeva, A. N., Amangeldikyzy, A., & Askarova, N. S. (2019). Patterns of beryllium distribution in rocks of Central Kazakhstan. Naukovyi Visnyk Natsionalnoho Hirnychoho Universytetu, (6), 5-10. https://doi.org/10.29202/nvngu/2019-6/1

20.      Portnov, V. S., Kopobayeva, A. N., Amangeldikyzy, A., & Askarova, N. S. (2019). The distribution of beryllium in magmatic rocks of Central Kazakhstan. News of the National Academy of Sciences of the Republic of Kazakhstan, Series of Geology and Technical Sciences, 2(434), 150-158. https://doi.org/10.32014/2019.2518-170X.49

21.      Lerman, A., & Meybeck, M. (Eds.) (1988). Physical and Chemical Weathering in Geochemical Cycles. (NATO Science Series C, Vol. 251). Springer Dordrecht. https://doi.org/10.1007/978-94-009-3071-1

22.      Rollinson, H. R. (1993). Using Geochemical Data: Evaluation, Presentation, Interpretation. London: Longman. ISBN: 9780582060713.

23.      Pirajno, F. (2009). Hydrothermal Processes and Mineral Systems. Springer Dordrecht. https://doi.org/10.1007/978-1-4020-8613-7

24.      Groves, D. I., & Santosh, M. (2024). Mineral Systems, Earth Evolution, and Global Metallogeny (1 st ed.). Elsevier. https://doi.org/10.1016/C2022-0-02818-X

25.      Guilbert, J. M., & Park, C. F. (2007). The Geology of Ore Deposits. Waveland Press. ISBN: 9781577666605.

26.      Colman, S. M., & Dethier, D. P. (Eds.) (1986). Rates of Chemical Weathering of Rocks and Minerals. Academic Press. ISBN 9780121814908.

27.      White, W. M. (2013). Geochemistry. Wiley-Blackwell. ISBN: 9780470656686.

28.      Heinrich, C. A. (2005). The chemistry of hydrothermal tin(-tungsten) ore deposition. Economic Geology, 100(7), 1287-1312. https://doi.org/10.2113/gsecongeo.100.7.1287

29.      Guilbert, J. M., & Park, C. F. Jr. (1986). The Geology of Ore Deposits. W. H. Freeman. https://doi.org/10.1007/BF01041818

30.      Ridley, J. (2013). Ore Deposit Geology. Cambridge: Cambridge University Press. ISBN: 9780521869510.

31.      Sillitoe, R. H. (2010). Porphyry copper systems. Economic Geology, 105(1), 3-41. https://doi.org/10.2113/gsecongeo.105.1.3

 

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