Gold recovery from waste fine carbon using acetone as solvent (Amesmessa gold mine, Algeria)

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Authors:


M.Louz*, orcid.org/0009-0009-0731-5236, Department of Process Engineering, Faculty of Science and Technology, Saad Dahlab University, Blida-1, Algeria; Laboratory of Energetic Applications of Hydrogen, Faculty of Science and Technology, Department of Process Engineering, Saad Dahlab university, Blida-1, Algeria, e-mail: This email address is being protected from spambots. You need JavaScript enabled to view it.

R.Issaadi, orcid.org/0009-0007-0687-7443, Department of Process Engineering, Faculty of Science and Technology, Saad Dahlab University, Blida-1, Algeria; Laboratory of Energetic Applications of Hydrogen, Faculty of Science and Technology, Department of Process Engineering, Saad Dahlab university, Blida-1, Algeria

M.Ferfar, orcid.org/0000-0002-2028-5213, Environmental Research Center, Annaba, Algeria

M.W.Naceur, orcid.org/0000-0003-3173-4632, Department of Process Engineering, Faculty of Science and Technology, Saad Dahlab University, Blida-1, Algeria; Laboratory of Water, Environment and Sustainable Development, Faculty of Science and Technology, Department of Process Engineering, Saad Dahlab University, Blida-1, Algeria

* Corresponding author e-mail: This email address is being protected from spambots. You need JavaScript enabled to view it.


повний текст / full article



Naukovyi Visnyk Natsionalnoho Hirnychoho Universytetu. 2024, (2): 060 - 066

https://doi.org/10.33271/nvngu/2024-2/060



Abstract:



Purpose.
The aim of this work at the first stage is to develop a new method to recover gold from waste fine loaded activated carbon. At the second stage, a new method is to be developed using less energy and less hazardous chemicals to recover gold from fine and coarse activated carbon in all the process of gold ore treatment.


Methodology.
The desorption of gold cyanide from the waste fine loaded activated carbon was processed by agitating the carbon on alkaline aqueous solution containing 20 % (v/v) of acetone (pH between 10 and 13) at room temperature.


Findings.
The application of the proposed method gave satisfactory results in terms of process efficiency, the time of operation and no use of hazardous chemicals such as cyanide. The efficiency is more than 96 %, the resident time – less than 3 h. As for the hazardous chemicals, there is no use of cyanide unlike in the conventional process.


Originality.
The use of acetone as an organic solvent makes the gold cyanide desorption from activated carbon operated at room temperature and in short time better than any other conventionel process.


Practical value.
This method allows to recover easily and economically the gold entrapped into waste activated carbon existing in a mining plant at room temperature in an agitating tank, pH = 10–13 with an efficiency over 96 %. This method can be a good alternative for all gold recovery processes from activated carbon used nowadays.



Keywords:
gold stripping, activated carbon, gold sorption and desorption, gold mining, organic gold elution

References.


1. Xia, J., Marthi, R., Twinney, J., & Ghahreman, A. (2022). A review on adsorption mechanism of gold cyanide complex onto activation carbon. https://doi.org/10.1016/j.jiec.2022.04.014.

2. Hilson, G., & Monhemius, A. J. (2006). Alternatives to cyanide in the gold mining industry: what prospects for the future? Journal of Cleaner Production, 14(12), 1158-1167. https://doi.org/10.1016/j.jclepro.2004.09.005.

3. de Andrade Lima, L. R. P., & Hodouin, D. (2006). Analysis of the gold recovery profile through a cyanidation plant. International Journal of Mineral Processing, 80(1), 15-26. https://doi.org/10.1016/j.minpro.2006.01.002.

4. Vences-Alvarez, E., Razo-Flores, E., Isabel Lázaro, I., Roberto Briones-Gallardo, R., Guillermo Velasco-Martínez, G., & Rangel-Mendez, R. (2017). Show moreGold recovery from very dilute solutions from a mine in closing process: Adsorption-desorption onto carbon materials. Journal of Molecular Liquids, 240, 549-555. https://doi.org/10.1016/j.molliq.2017.05.069.

5. Das Gracas Santos, N. T., Moraes, L. F., da Silva, M. G. C., & Vieira, M. G. A. (2020). Recovery of gold through adsorption onto sericin and alginate particles chemically crosslinked by proanthocyanidins. Journal of cleaner production, 253, 119925. https://doi.org/10.1016/j.jclepro.2019.119925.

6. Ubaldini, S., Massidda, R., Vegliò, F., & Beolchini, F. (2006). Gold stripping by hydro-alcoholic solutions from activated carbon: Experimental results and data analysis by a semi-empirical model. Hydrometallurgy, 81(1), 40-44. https://doi.org/10.1016/j.hydromet.2005.10.004.

7. Soleimani, M., & Kaghazchi, T. (2008). Gold recovery from loaded activated carbon using different solvents. Journal of the Chinese Institute of Chemical Engineers, 39(1), 9-11. https://doi.org/10.1016/j.jcice.2007.11.004.

8. Feng, D., H. Tan, & van Deventer, J. S. J. (2003). Ultrasonic elution of gold from activated carbon. Minerals Engineering, 16(3), 257-264. https://doi.org/10.1016/S0892-6875(02)00315-1.

9. Snyders, C. A., Bradshaw, S. M., Akdogan, G., & Eksteen, J. J. (2015). Factors affecting the elution of Pt, Pd and Au cyanide from activated carbon. Minerals Engineering, 80, 14-24. https://doi.org/10.1016/j.mineng.2015.06.013.

10. Rajasingam, R., Jayasinghe, N. S., Lucien, F. P., & Tran, T. (2006). Selective elution of the gold cyanide complex from anion exchange resin using mixed solvents. Minerals Engineering, 19(9), 896-903. https://doi.org/10.1016/j.mineng.2005.09.054.

11. Adams, C. R., Porter, C. P., Robshaw, T. T., Bezzina, J. P., Shields, V. R., Hides, A., …, & Ogden, M. D. (2020). An alternative to cyanide leaching of waste activated carbon ash for gold and silver recovery via synergistic dual-lixiviant treatment. Journal of Industrial and Engineering Chemistry, 92. https://doi.org/10.1016/j.jiec.2020.08.031.

12. Mansurov, Y. N., Miklin, Y. A., Miklin, N. A., & Nikol’skii, A. V. (2018). Methods and Equipment for Breaking Down Gold-Containing Concentrates from Lean Ores and Mining Industry Waste. Metallurgist, 62(1), 169-175. https://doi.org/10.1007/s11015-018-0640-z.

13. Plazinski, W., Rudzinski, W., & Plazinska, A. (2009). Theoretical models of sorption kinetics including a surface reaction mechanism: a review. Advances in colloid and interface science, 152(1-2), 2-13. https://doi.org/10.1016/j.cis.2009.07.009.

14. Haerifar, M., & Azizian, S. (2013). Mixed Surface Reaction and Diffusion-Controlled Kinetic Model for Adsorption at the Solid/Solution Interface. The Journal of Physical Chemistry C, 117(16), 8310-8317. https://doi.org/10.1021/jp401571m.

15. Azizian, S. (2004). Kinetic Models of Sorption: A Theoretical Analysis. Journal of Colloid and Interface Science, 276, 47. https://doi.org/10.1016/j.jcis.2004.03.048.

16. Chen, Y., Zi, F., Hu, X., Yang, P., Ma, Y., Cheng, H., ..., & Wang, C. (2020). The use of new modified activated carbon in thiosulfate solution: A green gold recovery technology. Separation and Purification Technology, 230, 115834. https://doi.org/10.1016/j.seppur.2019.115834.

17. Ho, Y.-S. (2006). Review of second-order models for adsorption systems. Journal of Hazardous Materials, 136(3), 681-689. https://doi.org/10.1016/j.jhazmat.2005.12.043.

18. Hoppen, M. I., Carvalho, K. Q., Ferreira, R. C., Passig, F. H., Pereira, I. C., Rizzo-Domingues, R. C. P., ..., & Bottini, R. C. R. (2019). Adsorption and desorption of acetylsalicylic acid onto activa­ted carbon of babassu coconut mesocarp. Journal of Environmental Chemical Engineering, 7(1), 102862. https://doi.org/10.1016/j.jece.2018.102862.

 

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