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Eco-friendly biosorbent based on local raw material: application to dye removal

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Category: Content №2 2024

Last Updated on 01 May 2024

Published on 30 November -0001

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Authors:

Z.Graba, orcid.org/0000-0002-6047-8933, University of Bejaia, Faculty of Exact Sciences, Laboratory of Materials Technology and Process Engineering (­LTMGP), Bejaia, Algeria

F.Ait Merzeg*2,3,4, orcid.org/0000-0003-1370-5977, Scientific and Technical Research Center in Physical and Chemical Analyses, Tipaza, Algeria; Research Unit in Physico-Chemical Analyzes of Fluids and Soils, Algiers, Algeria; Technical Platform for Physico-chemical Analyzes, Bejaia, Algeria

I.Akkari, orcid.org/0000-0003-1705-3910, University of Bejaia, Faculty of Exact Sciences, Laboratory of Materials Technology and Process Engineering (­LTMGP), Bejaia, Algeria

Y.Tiliouine, orcid.org/0009-0001-8473-7864, University of Bejaia, Faculty of Exact Sciences, Laboratory of Materials Technology and Process Engineering (­LTMGP), Bejaia, Algeria

M.M.Kaci, orcid.org/0000-0003-1863-0919, Laboratory of Reaction Engineering, Faculty of Mechanical and Process Engineering, Algiers, Algeria

K.Bachari, orcid.org/0000-0003-0624-8480, Scientific and Technical Research Center in Physical and Chemical Analyses, Tipaza, Algeria

* Corresponding author e-mail: This email address is being protected from spambots. You need JavaScript enabled to view it.

повний текст / full article

Naukovyi Visnyk Natsionalnoho Hirnychoho Universytetu. 2024, (2): 120 - 125

https://doi.org/10.33271/nvngu/2024-2/120

Abstract:

Purpose. A leading cause of water contamination is the widespread use of dyes, which are consumed in large amounts. The purpose of the present study was to investigate the potential of the Cactus paddle (CP) as an environmentally safe biosorbent for removing Basic Red 46 dye from aqueous media.

Methodology. Various analytical tools, comprising XRF, XRD, BET/BJH, FTIR, and pH_PZC methods, were used to examine the surface characteristics of the biosorbent. For assessing the ability of CP for BR46 adsorption, batch adsorption assays were performed.

Findings. An amount of 3.45 mg · g^-1 of BR46 was adsorbed at pH 7, 500 rpm and 293 K within 180 minutes. The isothermal data was described by both the Freundlich and the Langmuir equations with R²  0.984 and ²  0.01. The kinetics was well described by a PSO model, suggesting that physico-chemical interactions govern the adsorption process.

Originality. For the first time, the effective use of a local raw material resource CP as a biosorbent for the removal of BR46 dye has been substantiated.

Practical value. As a result of the findings of this study, it seems possible that CP can be regarded as a sustainable resource, which would create a possibility for addressing environmental concerns in the future.

Keywords: biosorbent Cactus paddle, adsorption, basic Red 46 dye

References.

1. Patra, T., Mohanty, A., Singh, L., Muduli, S., Parhi, P. K., & Sahoo, T. R. (2022). Effect of calcination temperature on morphology and phase transformation of MnO₂ nanoparticles: A step towards green synthesis for reactive dye adsorption. Chemosphere, 288, 132472. https://doi.org/ 10.1016/j.chemosphere.2021.132472.

2. Graba, Z., Akkari, I., Bezzi, N., & Kaci, M. M. (2022). Valorization of olive–pomace as a green sorbent to remove Basic Red 46 (BR46) dye from aqueous solution. Biomass Conversion and Biorefinery, 1-12. https://doi.org/10.1007/s13399-022-03639-y.

3. Miretzky, P., Munoz, C., & Carrillo-Chávez, A. (2008). Experimental binding of lead to a low cost on biosorbent: Nopal (Opuntia streptacantha). Bioresource Technology, 99(5), 1211-1217. https://doi.org/10.1016/j.biortech.2007.02.045.

4. López-González, H., Serrano-Gómez, J., & Olguín, M. T. (2012). Ectodermis of paddle cactus (Opuntia spp.) as biosorbent of chromium (VI) from aqueous solutions. Chemistry and Ecology, 28(5), 457-467. https://doi.org/10.1080/02757540.2012.666530.

5. Barka, N., Abdennouri, M., El Makhfouk, M., & Qourzal, S. (2013). Biosorption characteristics of cadmium and lead onto eco-friendly dried cactus (Opuntia ficus indica) cladodes. Journal of Environmental Chemical Engineering, 1(3), 144-149. https://doi.org/10.1016/j.jece.2013.04.008.

6. Barka, N., Ouzaouit, K., Abdennouri, M., & El Makhfouk, M. (2013). Dried prickly pear cactus (Opuntia ficus indica) cladodes as a low-cost and eco-friendly biosorbent for dyes removal from aqueous solutions. Journal of the Taiwan Institute of Chemical Engineers, 44(1), 52-60. https://doi.org/10.1016/j.jtice.2012.09.007.

7. Louati, I., Fersi, M., Hadrich, B., Ghariani, B., Nasri, M., & Mechichi, T. (2018). Prickly pear cactus cladodes powder of Opuntia ficus indica as a cost effective biosorbent for dyes removal from aqueous solutions. Biotech, 8, 1-10.

8. Akkari, I., Graba, Z., Bezzi, N., Kaci, M. M., Merzeg, F. A., Bait, N., ..., & Benguerba, Y. (2022). Effective removal of cationic dye on activated carbon made from cactus fruit peels: a combined experimental and theoretical study. Environmental Science and Pollution Research, 1-18. https://doi.org/10.1007/s11356-022-22402-4.

9. Akkari, I., Graba, Z., Pazos, M., Bezzi, N., Atmani, F., Manseri, A., & Kaci, M. M. (2023). Recycling waste by manufacturing biomaterial for environmental engineering: Application to dye removal. Biocatalysis and Agricultural Biotechnology, 50, 102709. https://doi.org/10.1016/j.bcab.2023.102709.

10. Baláž, M., Ficeriová, J., & Briančin, J. (2016). Influence of milling on the adsorption ability of eggshell waste. Chemosphere, 146, 458-471. https://doi.org/10.1016/j.chemosphere.2015.12.002.

11. Tran, H. N., Tomul, F., Ha, N. T. H., Nguyen, D. T., Lima, E. C., Le, G. T., ..., & Woo, S. H. (2020). Innovative spherical biochar for pharmaceutical removal from water: Insight into adsorption mechanism. Journal of hazardous materials, 394, 122255. https://doi.org/10.1016/j.jhazmat.2020.122255.

12. Akkari, I., Graba, Z., Pazos, M., Bezzi, N., Manseri, A., Derkaoui, K., & Kaci, M. M. (2023). NaOH-activated Pomegranate Peel Hydrochar: Preparation, Characterization and Improved Acebutolol Adsorption. Water, Air, & Soil Pollution, 234(11), 705. https://doi.org/10.1007/s11270-023-06723-9.

13. Yang, X., Zhu, W., Song, Y., Zhuang, H., & Tang, H. (2021). Removal of cationic dye BR46 by biochar prepared from Chrysanthemum morifolium Ramat straw: A study on adsorption equilibrium, kinetics and isotherm. Journal of Molecular Liquids, 340, 116617. https://doi.org/10.1016/j.molliq.2021.116617.

14. Konicki, W., Hełminiak, A., Arabczyk, W., & Mijowska, E. (2018). Adsorption of cationic dyes onto Fe@ graphite core–shell magnetic nanocomposite: Equilibrium, kinetics and thermodynamics. Chemical Engineering Research and Design, 129, 259-270. https://doi.org/10.1016/j.cherd.2017.11.004.

15. Senoussi, H., & Bouhidel, K. E. (2018). Feasibility and optimisation of a batch mode capacitive deionization (BM CDI) process for textile cationic dyes (TCD) removal and recovery from industrial wastewaters. Journal of Cleaner Production, 205, 721-727. https://doi.org/10.1016/j.jclepro.2018.09.026.

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